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CAS

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Diclofop-methyl, a colorless crystalline solid that is odorless and can also be commercially available as a clear to dark brown liquid with a typical solvent odor, is a selective post-emergence herbicide. It is decomposed by either strong acid or base and is used to control wild oats and annual grassy weeds in various grain and vegetable crops.

51338-27-3

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51338-27-3 Usage

Uses

Used in Agriculture:
Diclofop-methyl is used as a selective herbicide for controlling wild oats and annual grassy weeds in a variety of crops. This application is particularly important for maintaining crop health and yield.
Used in Grain Crops:
Diclofop-methyl is used as a herbicide for controlling weeds in grain crops such as barley, wheat, and rapeseed (canola). Its selective nature ensures that the target weeds are eliminated without causing significant harm to the desired crop.
Used in Vegetable Crops:
Diclofop-methyl is also used as a herbicide in vegetable crops, including carrots, celery, box, field and french beans, brassicas, parsnips, peas, potatoes, onions, sugar beets, and lettuce. This helps to improve the quality and yield of these crops by reducing competition from weeds.
Used in U.S. Restricted Use Pesticide (RUP):
Some uses of Diclofop-methyl are classified as U.S. Restricted Use Pesticide (RUP), indicating that its application requires specific knowledge and adherence to safety guidelines to minimize potential risks to human health and the environment.

Air & Water Reactions

Slightly soluble in water (3 mg/l).

Reactivity Profile

A bridged diphenyl.

Trade name

DICHLORDIPHENPROP?; HOELON?; HOELON? 3EC; HOE-GRASS?; HOEGRASS?; HOE? 23408; ILOXAN?; ILLOXAN?; ONE SHOT?[C]

Potential Exposure

Diclofop-methyl is a chlorophenoxy; aryloxyphenoxypropionate acid selective postemergenceherbicide used to control wild oats and annual grassy weeds in grain and vegetable crops: alfalfa, carrots, celery, box, field and French beans, barley, wheat, brassicas, parsnips, peas, potatoes, rapeseed (canola), soy beans, oilseed rape, onions, sugar beets and lettuce. Some uses are classified RUP

Environmental Fate

Biological. From the first-order biotic and abiotic rate constants of diclofop-methyl in estuarine water and sediment/water systems, the estimated biodegradation half-lives were 0.24–12.4 and 0.11–2.2 days, respectively (Walker et al., 1988).

Metabolic pathway

Two resistant biotypes of black-grass (Peldon A1 and Lincs. E1 of Alopecurus myosuroides) exhibit moderately enhanced metabolism of 14C-diclofop methyl. Diclofop methyl is hydrolyzed to the corresponding propionic acid which undergoes further degradation to give polar metabolites. The amounts of the metabolites depend on the metabolism activity of the individual biotypes. In wheat, three isomeric hydroxylated metabolites are identified in a major metabolic pathway after acid hydrolysis of the glucoside conjugates.

Shipping

UN3345 Phenoxyacetic acid derivative pesticide, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3348 Phenoxyacetic acid derivative pesticide, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous material. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required. Note: Commercial product may also be a liquid in a flammable carrier.

Incompatibilities

Incompatible with oxidizers, chlorates nitrates, peroxides, sulfuric acid, caustics, ammonia, aliphatic amines, alkanolamines, isocyanates, alkylene oxides, and epichlorohydrin.

Waste Disposal

In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office

Check Digit Verification of cas no

The CAS Registry Mumber 51338-27-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,1,3,3 and 8 respectively; the second part has 2 digits, 2 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 51338-27:
(7*5)+(6*1)+(5*3)+(4*3)+(3*8)+(2*2)+(1*7)=103
103 % 10 = 3
So 51338-27-3 is a valid CAS Registry Number.
InChI:InChI=1/C16H14Cl2O4/c1-10(16(19)20)9-21-12-3-5-13(6-4-12)22-15-7-2-11(17)8-14(15)18/h2-8,10H,9H2,1H3,(H,19,20)/p-1

51338-27-3 Well-known Company Product Price

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  • Sigma-Aldrich

  • (45442)  Diclofop-methyl  PESTANAL®, analytical standard

  • 51338-27-3

  • 45442-250MG

  • 272.61CNY

  • Detail

51338-27-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name diclofop-methyl

1.2 Other means of identification

Product number -
Other names methyl 2-[4-(2,4-dichlorophenoxy)phenoxy]propanoate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Herbicide
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:51338-27-3 SDS

51338-27-3Relevant articles and documents

NOXIOUS ARTHROPOD CONTROL AGENT CONTAINING AMIDE COMPOUND

-

, (2017/08/26)

An object of the present invention is to provide a compound having the controlling activity on a noxious arthropod, and a noxious arthropod controlling agent containing an amide compound of formula (I): wherein X represents a nitrogen atom or a CH group, p represents 0 or 1, A represents a tetrahydrofuranyl group or the like, R1, R2, R3, R4, R5, R6 and R7 represent a hydrogen atom or the like, n represents 1 or 2, Y represents an oxygen atom or the like, m represents any integer of 0 to 7, and Q represents a C1-8 chain hydrocarbon group optionally having a phenyl group or the like, has the excellent noxious arthropod controlling effect.

Herbicidal sulfonamides

-

, (2008/06/13)

Compounds of the formula: wherein, R1 is H or CH3; and, R2 is H, F, Cl or CH3;, exhibit herbicidal activity, especially selective activity on rape. The compounds may be made e.g. by reacting the appropriate arylsulfonyl isocyanate with the appropriate aminotriazine.

Herbicidal esters of D-1-(phenoxy-4-phenoxy)propionic acid

-

, (2008/06/13)

Optically active enantiomers of the formula I STR1 where R is a group of the formulae STR2 R1 and R2, among others, are halogen or CF3 and Z is a carboxyl, carboxylate, carboxylic acid ester, thioester, carbonamide, carboxylic acid anilide, carbohydrazide or thioamide group, are interesting herbicides the effect of which is considerably superior to that of the optically inactive racemates.

Furanyl oximes

-

, (2008/06/13)

Novel oxime ethers and oxime esters of the formula I given herein have various advantageous effects with regard to stimulation of plant growth, particularly in the early stage of development of the plant. Furthermore, such compounds have the property of rendering, in the sense of an antidote action, agricultural chemicals which would otherwise damage the plants (phytotoxic chemicals) more compatible with the cultivated plants. Herbicides that are insufficiently selective can be used for example in the presence of such oxime derivatives in specific cultivated crops for combating weeds, without disadvantageous consequences for the cultivated plants.

5,6-Dihydro-1,2,4,6-thiatriazin-5-one-1,1-dioxides

-

, (2008/06/13)

5,6-Dihydro-1,2,4,6-thiatriazin-5-one-1,1-dioxides of the formula STR1 where R1 is hydrogen, a metal atom or an unsubstituted or substituted ammonium radical, R2 is a saturated or unsaturated straight-chain aliphatic radical of up to 10 carbon atoms, a cycloaliphatic radical or 3 to 7 carbon atoms, a branched saturated or unsaturated aliphatic radical of 3 to 10 carbon atoms, a halogen-, alkoxy- or alkylmercapto-substituted aliphatic radical of 2 to 10 carbon atoms tetrahydrofuryl substituted methyl, a cycloalkoxy-substituted aliphatic radical of 4 to 10 carbon atoms, unsubstituted or halogen-substituted benzyl or phenyl, halophenyl, or alkylphenyl of a total of up to 10 carbon atoms, R3 is hydrogen, a straight-chain aliphatic radical of up to 10 carbon atoms, a cycloaliphatic radical of 3 to 7 carbon atoms, a branched aliphatic radical of 3 to 10 carbon atoms, haloalkyl, or alkoxyalkyl of 2 to 10 carbon atoms and X is oxygen and may also be sulfur if R2 is unsubstituted or halogen-substituted benzyl, processes for their preparation, and herbicides containing the above compounds.

Process for the manufacture of (phenoxy or benzyl)-phenoxypropionic acid methyl esters

-

, (2008/06/13)

(Phenoxy- or benzyl)-phenoxypropionic acid methyl esters are produced by esterification of the corresponding anhydrous alkali metal salts with half the molar amount of dimethyl sulfate at a temperature exceeding 120° C.

4-Phenoxy-phenoxy-alkane-carboxylic acid derivatives and process for their manufacture

-

, (2008/06/13)

Novel 4-phenoxy-phenoxy-alkane-carboxylic acid derivatives of the formula I STR1 in which R1 stands for hydrogen, methylthio, cyclopentyl, cyclohexyl, phenyl, methylcyclohexyl, ethylcyclohexyl, or R1 and R3 together stand for a --CH=CH--CH=CH-- bridge or--unless at least one of the substituents R2 to R8 stands for hydrogen, or if R9 stands for a radical having at least 2 carbon atoms--for chlorine, R2 and R3, independent of one another, each stands for hydrogen, chlorine or alkyl of 1 to 4 carbon atoms, R4 stands for hydrogen, chlorine, alkyl of 1 to 4 carbon atoms, cyclopentyl, cyclohexyl, methylcyclohexyl or R3 and R4 together stand for a --CH=CH--CH=CH-- bridge, R5, R6 and R7, independent of one another, each stands for hydrogen or alkyl of 1 to 4 carbon atoms, R8 stands for hydrogen, alkyl of 1 to 4 carbon atoms or allyl, R9 stands for alkyl of 1 to 10 carbon atoms or phenyl and X stands for hydrogen, the cation of a physiologically acceptable inorganic or organic base of a hydrocarbon radical of 1 to 10 carbon atoms, having a strong action on the lipide and cholesterine metabolism and a process for their manufacture.

Synthesis and Herbicidal Activity of the D- and L-Methyl 2--propionate Enantiomers

Nestler, Hans Juergen,Bieringer, Hermann

, p. 366 - 371 (2007/10/02)

The D- and L-enantiomers of the wild oat herbicide diclofop-methyl (title compound) were prepared utilizing resolution operations and by synthetic routes with optically active compounds as starting material.The dextro-rotatory product which the D(R)-configuration can be attributed to, was found to be the herbicidally active species. - Keywords: Phenoxy-phenoxy-propionic Acid Ester, Diclofop-methyl, Stereoisomers, Grass Herbicide

Phenylglyoxylonitrile-2-oxime-cyanomethyl ether as plant growth regulator

-

, (2008/06/13)

Phenylglyoxylonitrile-2-oxime-cyanomethyl ether of the formula STR1 and compositions containing it, have various advantageous effects with regard to regulation of plant growth. Furthermore, this compound and its compositions have the property of rendering, in the sense of an antidote (safening) action, agricultural chemicals which would otherwise damage the plants more compatible with cultivated plants. Strong herbicides, for example chloroacetanilides or thiolcarbamates, can be used in the presence of such safening agents in specific crops such as sorghum and rice for combatting weeds without disadvantageous consequences for the crops. The safeners are preferably applied to the crop seeds prior to planting.

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