919-30-2Relevant articles and documents
THE PROCESS FOR THE PREPARATION AND USE OF HAIR TREATMENT COMPOSITIONS CONTAINING ORGANIC C1-C6 ALKOXY SILANES
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, (2022/01/12)
The subject of the present application is a method for the preparation and use of an agent for the treatment of keratinous material, in particular human hair, comprising the following steps: (1) Mixing one or more organic C1-C6 alkoxy silanes with water,(2) optionally, partial, or complete removal from the reaction mixture of the C1-C6 alcohols liberated by the reaction in step (1),(3) if necessary, addition of one or more cosmetic ingredients,(4) Filling of the preparation into a packaging unit,(5) Storage of the preparation in the packaging unit for a period of at least about 5 days; and(6) Application of the preparation on the keratinous material.
Structure-Property Relationships of Silylamine-Type Reversible Ionic Liquids for Use as a Switchable Electrolyte
Jung, Sungyup,Podder, Showmik,Chen, Josephine,Biddinger, Elizabeth J.
, (2021/04/23)
Switchable electrolytes, whose properties (i.e., conductivity and polarity) can be switched dramatically are very useful. They can address problems associated with multiple electrochemical systems: (1) the need to separate products from the electrolyte after electro-organic syntheses, and; (2) the desire to stop the acceleration of electrochemical reactions in energy storage devices during thermal excursions. Silylamine-type reversible ionic liquids (RevILs) in co-solvents were used as switchable electrolytes in this work. The silylamine RevILs in co-solvents can have a dramatic change in conductivity when switching from a RevIL state to a molecular liquid (state) when heat is applied. The silylamines also have significant changes in polarity with switching. The fundamental silylamine structure-property relationships that can be tuned to control relevant properties such as conductivity, viscosity, thermal switch temperature, and solubility were investigated. In addition, these silylamine RevILs were tested with the addition of metal salts, which were found to increase the conductivity in both the RevIL and ML states. By tailoring the silylamine RevIL structures, the thermo-physical properties for the electrochemical application can be met.
AGENT FOR DYEING HAIR, CONTAINING AT LEAST ONE ORGANIC SILICON COMPOUND, A COLORING COMPOUND AND A FILM-FORMING, HYDROPHILIC POLYMER
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, (2021/11/26)
The subject of the present disclosure is a composition for coloring keratinous material, in particular human hair, containing in a cosmetic carrier (a) at least one organic silicon compound selected from silanes having one, two or three silicon atoms, said organic silicon compound further comprising one or more basic chemical functions and one or more hydroxyl groups or hydrolysable groups per molecule,(b) at least one colorant compound from the group of pigments and/or direct dyes, and(c) at least one film-forming hydrophilic polymer.
METHOD FOR TREATING HAIR, COMPRISING THE APPLICATION OF AN ORGANIC SILICON COMPOUND, AN ALKALISING AGENT AND A FILM-FORMING POLYMER
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, (2022/01/08)
It is an object of the present disclosure to provide a method for treating keratinous material, in particular human hair, comprising the following steps: Application of a water-containing agent (a) to the keratinous material, wherein the agent (a) has and contains a pH of at least 9.6:(a1) at least one organic silicon compound selected from the group including silanes having one, two or three silicon atoms, and(a2) at least one alkalizing agent selected from the group including ammonia, alkanolamines and basic amino acids, andApplication of an agent (b) to the keratinous material, wherein the agent (b) includes:(b1) at least one film-forming polymer.
PROCESS FOR DYEING HAIR
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, (2021/01/22)
The subject of the present disclosure is a process for dyeing human hair, in which a pretreatment agent (A) which contains at least one organic silicon compound of the formula (I) and/or (II) and contains no direct dyes and no pigments, anda colorant (B) which contains at least one organic silicon compound of the formula (I) and/or (II) and further contains at least one colorant compound from the group of direct dyes and/or pigments, can be applied to the hair, wherein the organic silicon compounds of formulae (I) and (II) are defined as follows [in-line-formulae]R1R2N-L-Si(OR3)a(R4)b??(I),[/in-line-formulae] [in-line-formulae](R5O)c(R6)dSi-(A)e-[NR7-(A′)]f—[O-(A″)]g-[NR8-(A′″)]h—Si(R6′)d′(OR5′)c′??(II).[/in-line-formulae]
(Dicyclopentadiene) platinum(II) dichloride: An efficient catalyst for the hydrosilylation reaction between alkenes and triethoxysilane
Wu, Huarui,Zheng, Chaoyue,Chen, Naiwu,Zhu, Jie,Gao, Deqing
supporting information, p. 1576 - 1578 (2017/04/03)
(Dicyclopentadiene) platinum(II) dichloride was found to be an efficient hydrosilylation catalyst (homogeneous) upon a wide variety of functionalized alkenes and alkenes terminated with chemical moieties (diphenyl amino-, N-carbazol- and N-isoindoline-1,3-dione-). It is noteworthy that the hydrosilylation of aminated alkenes with triethoxysilane exhibited the yield of over 70% and the selectivity (γ-isomer/β-isomer) of more than 3/1. Due to steric hindrance lowering Markovnikov probability, the alkenes with big terminal moieties (diphenyl amino-, N-carbazol- and N-isoindoline-1,3-dione-) presented the high ratio of anti-Markovnikov isomers. The strategy of the hydrosilylation of the protected diamino chelating alkene was developed.
Study of Karstedt's Catalyst for Hydrosilylation of a Wide Variety of Functionalized Alkenes with Triethoxysilane and Trimethoxysilane
Pan, Zhenhuan,Liu, Minglun,Zheng, Chaoyue,Gao, Deqing,Huang, Wei
supporting information, p. 1227 - 1230 (2017/09/02)
The hydrosilylation is one of the most important methods for the synthesis of organosilicon compounds. Karstedt's catalyst [Ptn(H2C=CHSiMe2OSiMe2CH=CH2)m] is a kind of platinum catalyst which is widely used in the hydrosilylation. In this paper, we studied the catalytic activity of Karstedt's catalyst for the hydrogenation of olefins and especially aminated alkenes with trimethoxysilane and triethoxysilane, and demonstrated the excellent performance in terms of the yield and selectivity.
Synthesis method of aminopropyl triethoxysilane
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Paragraph 0017; 0020, (2017/01/02)
The invention relates to a synthesis method of aminopropyl triethoxysilane and belongs to the technical field of fine chemical engineering.According to the method, acetone and allyl amine are put into a reactor according to a proportion, a water absorbing agent is added, after a stirring and temperature-raising reaction, reactants are distilled and filtered, filter residues are reused after being regenerated, filter liquor and triethoxysilane are subjected to an addition reaction through a Custer catalyst, purified products obtained after being distilled react with deionized water, and after low-boiling-point acetone is obtained through distillation, an aminopropyl triethoxysilane product is obtained.The yield of the aminopropyl triethoxysilane product is high, energy consumption is low, production cost is low, side products and raw materials can be recycled, and environmental pollution is avoided.
Method for preparing organic silicon by passage reaction device
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Paragraph 0051, (2016/10/17)
The invention provides a method for preparing organic silicon by a passage reaction device. Under the condition of main catalysts Z, hydrogen-containing silane X and an unsaturated compound Y are introduced into the passage reaction device; hydrosilylation reaction is performed to prepare the organic silicon, wherein the hydrogen-containing silane X has the structure being HSiRR'Cl, in the formula, R and R' are independently C1 to C16 alkyl or alkoxy; a=1, 2 or 3; b, c and d are respectively and independently 0, 1, 2 or 3; the unsaturated compound Y is a monoene compound or single-alkyne compound; the main catalysts Z are one or several mixed ones of single-component complexes or multi-component complexes of Pt, Pd, Rh, Ru, Cu, Ag, Au or Ir; the passage surface in which reaction flow contacts is subjected to inactivation treatment by an activating agent Z. The problems of long reaction period, poor stability and the like of large-sized reaction equipment are solved; the problem that mixing, pre-reaction and afterreaction are separated and are performed in multi-unit equipment is solved.
Process for manufacturing polysiloxane microcapsules that are functionalized and are not very porous
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Page/Page column 4, (2016/09/26)
A method is provided for encapsulating products that can have lipophilic or hydrophilic, including volatile, properties in a polysiloxane membrane that is particularly impervious. A method is also provided for evaluating the imperviousness of capsules. The present method includes the following steps: a) formation of droplets by an emulsion between an oily phase containing the product to be encapsulated and an acidic aqueous phase heated to around 50° C. and in the presence of surfactants; b) addition and hydrolysis of at least one silane in order to obtain a silanol; c) increasing the pH in order to start condensation of the silanol to form a first membrane around the droplets of the product to be encapsulated; d) lowering the pH; e) increasing the pH, optionally preceded by adding a silane, in order to obtain a new condensation of silanol around the droplets of the product to be encapsulated.
